Molecular tectonics: generation and structural studies on 1- and 2D coordination networks based on a meta-cyclophane in 1,3-alternate conformation bearing four pyrazolyl units and cobalt, zinc and copper cations.

Date publication

août 2009

Auteurs

Membres identifiés du Cancéropôle Est :
Dr PLANEIX Jean-Marc

Tous les auteurs :
Ehrhart J, Planeix JM, Kyritsakas-Gruber N, Hosseini MW

Lien Pubmed

https://www.ncbi.nlm.nih.gov/pubmed/19655064

Résumé

The combination of a [1111] metacyclophane blocked in 1,3-alternate conformation and bearing four pyrazolyl coordinating units with MX(2) (M = Co, Zn and X = Cl or Br) leads to the formation of crystals formed by packing of 2D coordination networks. In the case of CuBr(2), the formation of a 1D network was observed. Structural studies by X-ray diffraction methods on single crystals were performed on all cases reported.

Référence

Dalton Trans. 2009 Aug 28;(32):6309-14