Fiche publication


Date publication

août 2019

Journal

Chirality

Auteurs

Membres identifiés du Cancéropôle Est :
Dr BELLEMIN-LAPONNAZ Stéphane


Tous les auteurs :
Torres-Werlé M, Heinrich B, Maisse-François A, Bellemin-Laponnaz S

Résumé

We report the synthesis of chiral enantiopure polytopic bridging ligands, which may lead to the formation of metallosupramolecular polymers with zinc (II) as metal linker. We show that chiral C -symmetric bisoxazoline ligands are useful moieties to efficiently generate heterochiral complexes and thus polymeric entities. The corresponding metallopolymers were further characterized by powder X-ray diffraction (PXRD) to obtain information on the level of crystallinity of our different metallopolymers.

Mots clés

chiral bisoxazoline, metallopolymer, polytopic ligand, zinc

Référence

Chirality. 2019 Aug 22;: