BODIPY atropisomer interconversion, face discrimination, and superstructure appending.

Date publication

mars 2016

Journal

Chemical communications (Cambridge, England)

Auteurs

Membres identifiés du Cancéropôle Est :
Dr DECREAU Richard

Tous les auteurs :
Doulain PE, Goze C, Bodio E, Richard P, Decréau RA

Lien Pubmed

https://www.ncbi.nlm.nih.gov/pubmed/26927530

Résumé

A strategy was developed to append sterically hindered apical pickets on both faces of the BODIPY platform to prevent stacking and aggregation. Ortho-substitution of both the meso-phenyl ring and the boron-bound catechol affords the right directionality to append pickets, achieve face discrimination, featuring two interconvertible atropisomers, and is reminiscent of the picket-fence strategy in porphyrins.

Référence

Chem. Commun. (Camb.). 2016 Mar 25;52(24):4474-7