Fiche publication
Date publication
septembre 2021
Journal
Organic letters
Auteurs
Membres identifiés du Cancéropôle Est :
Dr SPECHT Alexandre
,
Dr GARNIER Delphine
Tous les auteurs :
Chaud J, Morville C, Bolze F, Garnier D, Chassaing S, Blond G, Specht A
Lien Pubmed
Résumé
We herein report the design, synthesis, and photophysical characterization of extended and rigid coumarinyl derivatives showing large two-photon sensitivities ( ≤ 125 GM) at 740 and 800 nm. To efficiently synthesize these complex photoremovable protecting groups (PPGs), we used step-economic domino reactions. Moreover, those new coumarinyl PPGs display unique bathochromic shifts (≤100 nm) of the uncaging subproducts as a result of the formation of a more conjugated fulvene moiety.
Référence
Org Lett. 2021 Sep 10;:
