Fiche publication


Date publication

avril 2022

Journal

Nanomaterials (Basel, Switzerland)

Auteurs

Membres identifiés du Cancéropôle Est :
Dr CHERIOUX Frédéric


Tous les auteurs :
Guan L, Palmino F, Lacroix JC, Chérioux F, Sun X

Résumé

Polymers obtained by on-surface chemistry have emerged as a class of promising materials. Here, we propose a new strategy to obtain self-assembled 1D polymers by using photochemical [2+2] cyclo-addition or by using a mild thermal annealing. All nanostructures are fully characterized by using scanning tunneling microscopy at ambient conditions on a graphite surface. We demonstrated that nature of the stimulus strongly alters the overall quality of the resulting polymers in terms of length and number of defects. This new way is an efficient method to elaborate on-surface self-assembled 1D polymers.

Mots clés

1D polymers, cyclo-addition, on-surface synthesis, scanning tunnelling microscopy

Référence

Nanomaterials (Basel). 2022 Apr 13;12(8):