Dynamic stereoisomerization in inherently chiral bimetallic [2]catenanes.

Date publication

avril 2015

Journal

Chemical communications (Cambridge, England)

Auteurs

Membres identifiés du Cancéropôle Est :
Dr CHARBONNIERE Loïc

Tous les auteurs :
Prakasam T, Lusi M, Nauha E, Olsen JC, Sy M, Platas-Iglesias C, Charbonnière LJ, Trabolsi A

Lien Pubmed

https://www.ncbi.nlm.nih.gov/pubmed/25664727

Résumé

Stereoisomerization and the unprecedented phenomenon of metal translocation in the absence of redox processes were probed in two inherently chiral bimetallic [2]catenanes by using a combination of variable-temperature (1)H NMR and CD spectroscopies, X-ray crystallography, and DFT calculations.

Mots clés

Catenanes, chemistry, Cations, Divalent, Coordination Complexes, chemistry, Crystallography, X-Ray, Magnetic Resonance Spectroscopy, Models, Molecular, Molecular Conformation, Stereoisomerism, Thermodynamics, Zinc, chemistry

Référence

Chem. Commun. (Camb.). 2015 Apr 7;51(27):5840-3