Synthesis and structural studies of metallamacrotricycles based on a metacyclophane in 1,3-alternate conformation bearing four imidazolyl units.
Fiche publication
Date publication
avril 2009
Auteurs
Membres identifiés du Cancéropôle Est :
Dr PLANEIX Jean-Marc
Tous les auteurs :
Ehrhart J, Planeix JM, Kyritsakas-Gruber N, Hosseini MW
Lien Pubmed
Résumé
The combination of a [1111]metacyclophane blocked in 1,3-alternate conformation and bearing four imidazole units with MX2 (M = Co, Cu, Zn and Hg; X = Cl or Br) complexes leads to the formation of a series of analogous neutral metallamacrotricycles. In all cases, the structure of the binuclear complexes has been studied by X-ray diffraction methods on single crystals.
Référence
Dalton Trans. 2009 Apr 14;(14):2552-7