Dynamic Diels-Alder Reactions of 9,10-Dimethylanthracene: Reversible Adduct Formation, Dynamic Exchange Processes and Thermal Fluorescence Modulation
Fiche publication
Date publication
avril 2009
Auteurs
Membres identifiés du Cancéropôle Est :
Pr LEHN Jean-Marie
Tous les auteurs :
Reutenauer P, Boul PJ, Lehn JM
Lien Pubmed
Résumé
Studies of the Diels-Alder reactions between 9,10-dimethylanthracene and cyano-functionalized dienophiles led to the identification and characterization of new dynamic systems under ambient conditions. Among these dienophiles were tricyanoethynylethylene derivatives, which gave access to reversible thermal switching of fluorescent properties through binding to and release of the dimethylanthracene partner. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
Référence
Eur J Org Chem. 2009 Apr;11:1691-7