Molecular tectonics: on the role of counter-ions in the dimensionality of silver coordination networks.
Fiche publication
Date publication
novembre 2005
Auteurs
Membres identifiés du Cancéropôle Est :
Dr PLANEIX Jean-Marc
Tous les auteurs :
Pocic D, Planeix JM, Kyritsakas N, Jouaiti A, Hosseini MW
Lien Pubmed
Résumé
The role played by different anions (XF6- (X = P, As, Sb), BF4-) on the connectivity of coordination networks formed by a combination of different silver salts and an organic tecton based on piperazine bearing two pyridine units has been studied in the crystalline phase by X-ray diffraction on single crystal. All four weakly coordinating anions lead to the formation of analogous 2-D coordination networks. For the isostructural anions XF6- (X = P, As, Sb) the crystals are isomorphous.
Référence
Crystengcomm. 2005 Nov 7;7:624-8.