Lipophilic phthalocyanines for their potential interest in photodynamic therapy: synthesis and photo-physical properties.

Fiche publication


Date publication

novembre 2013

Auteurs

Membres identifiés du Cancéropôle Est :
Dr FROCHOT Céline, Dr VANDERESSE Régis


Tous les auteurs :
Moussaron A, Arnoux P, Vanderesse R, Sibille E, Chaimbault P, Frochot C

Résumé

Several phthalocyanines with different peripheral substituents were prepared and characterized by MALDI-TOF, H-1 NMR, UV-vis, fluorescence, and singlet oxygen quantum yields and retention time in HPLC normal phase. Zinc was used as a central metal ion to increase the photodynamic therapy efficiency. Phthalonitrile or 4-nitro phthalonitriles were used as starting materials. The influence of lipophilicity on the photophysical and photochemical properties was evaluated. (C) 2013 Elsevier Ltd. All rights reserved.

Référence

Tetrahedron. 2013 Nov 25;69(47):10116-22.