Metal-ion-induced shape switching: Stereoselective formation of a dinuclear Hg(II) double helicate from a hydrazonobis(acylhydrazone) ligand.
Fiche publication
Date publication
juin 2012
Auteurs
Membres identifiés du Cancéropôle Est :
Pr LEHN Jean-Marie
Tous les auteurs :
Schaeffer G, Harrowfield JM, Lehn JM, Hirsch AKH
Lien Pubmed
Résumé
The unsymmetrical hydrazonobis(acylhydrazone) ligand L exists in solution as a mixture of isomers but complexes to Hg(II) with a major conformational change, affording a mixture of parallel and antiparallel binuclear double helicates. On crystallisation of the triflate salt, however, the antiparallel strand isomer is selected presumably due to the optimisation of several weak interactions. (c) 2012 Elsevier Ltd. All rights reserved.
Référence
. 2012 Jun 28;41(1):40-3.