Generation of metallosupramolecular polymer gels from multiply functionalized grid-type complexes.
Fiche publication
Date publication
janvier 2012
Auteurs
Membres identifiés du Cancéropôle Est :
Pr LEHN Jean-Marie
Tous les auteurs :
Hardy JG, Cao XY, Harrowfield J, Lehn JM
Lien Pubmed
Résumé
A ditopic ligand (1), containing two tridentate bis(acylhydrazone) subunits and bearing both long alkyl chains and hydrogen-bonding groups, has been synthesised. Metal cation binding in the presence of a base leads to hierarchical self-assembly, forming first a neutral [2 x 2] grid-type complex (2) that hierarchically assembles into metallosupramolecular polymer gels in toluene.
Référence
. 2012;36(3):668-73.