A new hydrogen bonding motif involved in self-recognition in the solid state by functionalised macrocycles.
Fiche publication
Date publication
janvier 2011
Auteurs
Membres identifiés du Cancéropôle Est :
Pr LEHN Jean-Marie
Tous les auteurs :
Brelot L, Cao XY, Harrowfield J, Lehn JM, Rissanen K, Russo L
Lien Pubmed
Résumé
Self-recognition within the crystal lattices of three functionalised macrocycles results in the formation of arrays of remarkably similar hermaphroditic pairs of macrocycles. In the case of two of the macrocycles containing acylhydrazine substituents, a hitherto unknown recognition pattern is found in the interaction of the hydrazine moiety with crown-ether oxygen atoms.
Référence
. 2011;13(7):2346-9.