Radical Smiles Rearrangement: An Update.
Fiche publication
Date publication
juillet 2016
Journal
Molecules (Basel, Switzerland)
Auteurs
Membres identifiés du Cancéropôle Est :
Pr SAPI Janos, Dr GERARD Stéphane
Tous les auteurs :
Allart-Simon I, Gérard S, Sapi J
Lien Pubmed
Résumé
Over the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of this approach, especially if it is incorporated into a domino process, for the preparation of polyfunctionalized complex molecules.
Référence
Molecules. 2016 Jul;21(7):